By ANDY FLEMING
Comets like Halley’s can be a breeding ground
for complex molecules such as dipeptides. Comets colliding with Earth could
have delivered these molecules and seeded the growth of more complex proteins
and sugars necessary for life. Courtesy of NASA.
It’s among the most ancient of questions: What
are the origins of life on Earth?
A new experiment simulating conditions in deep
space reveals that the complex building blocks of life could have been created
on icy interplanetary dust and then carried to Earth, jump-starting life.
Chemists from the University of California,
Berkeley, and the University of Hawaii, Manoa, showed that conditions in space
are capable of creating complex dipeptides – linked pairs of amino acids – that
are essential building blocks shared by all living things. The discovery opens
the door to the possibility that these molecules were brought to Earth aboard a
comet or possibly meteorites, catalysing the formation of proteins
(polypeptides), enzymes and even more complex molecules, such as sugars, that
are necessary for life.
“It is fascinating to consider that the most
basic biochemical building blocks that led to life on Earth may well have had
an extra-terrestrial origin,” said UC Berkeley chemist Richard Mathies,
coauthor of a paper published online last week and scheduled for the March 10
print issue of The Astrophysical Journal.
While scientists have discovered basic organic
molecules, such as amino acids, in numerous meteorites that have fallen to
Earth, they have been unable to find the more complex molecular structures that
are prerequisites for our planet’s biology. As a result, scientists have always
assumed that the really complicated chemistry of life must have originated in
Earth’s early oceans.
In an ultra-high vacuum chamber chilled to 10
degrees above absolute zero (10 Kelvin), Seol Kim and Ralf Kaiser of the
Hawaiian team simulated an icy snowball in space including carbon dioxide,
ammonia and various hydrocarbons such as methane, ethane and propane. When
zapped with high-energy electrons to simulate the cosmic rays in space, the
chemicals reacted to form complex, organic compounds, specifically dipeptides,
essential to life.
At UC Berkeley, Mathies and Amanda Stockton then
analysed the organic residues through the Mars Organic Analyser, an instrument
that Mathies designed for ultrasensitive detection and identification of small
organic molecules in the solar system. The analysis revealed the presence of
complex molecules – nine different amino acids and at least two dipeptides –
capable of catalysing biological evolution on earth.
Original Source: University of California at
Berkeley

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